The real world isn’t single wavelength
The sun, being a massive ball of plasma, among basically any other white light source, will be emitting photons across the entire visible spectrum — whatever reaches our eye at any given moment will rarely be a single wavelength of photons, meaning we really need to look at the combined effect of multiple wavelengths hitting our cones.
This will create situations in which cones are stimulated in ways that single wavelength light cannot, leading to us seeing non-spectral colors.
