The real world isn’t single wavelength
A single photon having a colour is nice and all, but in bright daylight, around 4,000,000,000,000,000 photons of varying wavelengths will hit your retina every second — so we really need to look at the combined effect of multiple wavelengths hitting our cones to understand colour in full.
In particular, two photons can stimulate cones in ways that a single photon cannot, leading to us seeing non-spectral colours.
